: 147-14-8EC-No. It is paramagnetic with one unpaired electron per molecule. Upon formation of H2O multilayers and merging of adjacent adsorbed H2O clusters, interactions between mobile Na+ ions, CuPc(SO3 Federal government websites often end in .gov or .mil. 1c. [4] Substituted phthalocyanine complexes often have much higher solubility. Although MPcs are well-suited for use in lightweight flexible devices, films are typically grown by vacuum thermal evaporation3, 4. 517, 20162022 (2009). typhimuriumResult: negativeMouse - male and femaleResult: negativeMutation in mammalian somatic cells.CarcinogenicityIARC: No component of this product present at levels greater than or equal to 0.1% isidentified as probable, possible or confirmed human carcinogen by IARC.No component of this product present at levels greater than or equal to 0.1% isidentified as probable, possible or confirmed human carcinogen by IARC.NTP: No component of this product present at levels greater than or equal to 0.1% isidentified as a known or anticipated carcinogen by NTP.No component of this product present at levels greater than or equal to 0.1% isidentified as a known or anticipated carcinogen by NTP.OSHA: No component of this product present at levels greater than or equal to 0.1% ison OSHAs list of regulated carcinogens.No component of this product present at levels greater than or equal to 0.1% ison OSHAs list of regulated carcinogens.Reproductive toxicityNo data availableNo data availableSpecific target organ toxicity - single exposureNo data availableSpecific target organ toxicity - repeated exposureNo data availableAspiration hazardNo data availableAdditional InformationRepeated dose toxicity - Rat - male and female - Oral - No observed adverse effect level -1,000 mg/kgRTECS: GL8510000, ToxicityToxicity to fish mortality LC50 - Danio rerio (zebra fish) - > 100 mg/l - 96 h(OECD Test Guideline 203)mortality LC50 - Cyprinus carpio (Carp) - > 100 mg/l - 96 h(OECD Test Guideline 203)Toxicity to daphnia and other aquatic invertebratesImmobilization EC50 - Daphnia magna (Water flea) - > 500 mg/l -48 h(Directive 67/548/EEC, Annex V, C.2. * Items in stock locally ship in 1-2 business days. See this image and copyright information in PMC. 2018 Jul 18;10(28):24201-24208. doi: 10.1021/acsami.8b07377. Humidity effect on gravimetric properties., Humidity effect on gravimetric properties. It is paramagnetic with one unpaired electron per molecule. Request PDF | Soluble Copper Phthalocyanine Applied for Organic Solar Cells | A soluble derivative of copper phthalocyanine, that is 2,9,16,23-tetra carboxyl copper phthalocyanine (CuTCPc), is . CuPcTs films were deposited from solution on pre-cleaned 5MHz AT-cut gold-coated quartz crystal microbalance (QCM) crystals with 1cm2 active electrode area, conductive n-doped SiO2 substrates, and undoped SiO2 substrates with pre-patterned gold interdigitated electrodes (10nm thickness, 2m spacing, 100 digits per electrode). (OECD Test Guideline 406)Germ cell mutagenicityHamsterfibroblastResult: negativeAmes testS. 2011;95:19701973. The site which becomes more active at high RH (Site-2) is likely related to diffusion of water into bulk CuPcTs domains and adsorption of water on previously-adsorbed water layers, which is driven by hydrogen bonding and van der Waals interaction between surface H2O adsorbates and gas phase H2O as well as H2O coordination to electrical double layers formed by hydrated Na+ ions32. the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in doi: 10.1016/j.apsusc.2004.11.036. The Journal of Physical Chemistry C Copper (II) 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecafluoro-29H,31H-phthalocyanine (F16CuPc) is an organic molecule that can be used as an electron transporting material with good air-stability and an electron mobility of 0.11 cm2/Vs . The images or other third party material in this article are included in the articles Creative Commons license, unless indicated otherwise in a credit line to the material. : 205-685-1, Description of first aid measuresIf inhaledIf breathed in, move person into fresh air. The substance is practically insoluble in water (<0.1g/100ml at 20C (68F)),[34] but soluble in concentrated sulfuric acid. Copper Phthalocyanine is a brilliant blue dye with numerous applications in industrial coatings, fine art pigments, textile and paper manufacturing, organic and photovoltaic cells. Water crowding at hydrophilic sulfonyl/salt groups leads to dissociation of Na, Multimode sensing and detection limits. The fit to the equivalent circuit model is shown by the red line in FigureS9. Areas of interest are the oxygen reduction reaction and the sweetening of gas streams by removal of hydrogen sulfide. 1,3-Diiminoisoindolene, the intermediate formed during phthalocyanine manufacture, used in combination with a copper salt affords the dye GK 161. Molecular Crystals and Liquid Crystals Investigation of gas-sensing properties of copper phthalocyanine films. Error bars correspond to uncertainty in R/R0 due to low signal to noise ratio. We (1 . Hamam, K. J., Al-Amar, M. M., Mezei, G., Guda, R. & Burns, C. High dielectric constant response of modified copper phthalocyanine. Anyone you share the following link with will be able to read this content: Sorry, a shareable link is not currently available for this article. Integration of an M-phthalocyanine layer into solution-processed organic photovoltaic cells for improved spectral coverage. The absorption spectrum of ZnPc-BODIPY pentad covers most of the visible region Structurally larger analogues include naphthalocyanines. Magnetic Properties of a Terbium-[1]Ferrocenophane Complex: Analogies between Lanthanide-Ferrocenophane and Lanthanide-Bis-phthalocyanine Complexes. [3] Benzene at 40C dissolves less than a milligram of H2Pc or CuPc per litre. Impedance was measured in the 1Hz 8MHz frequency range by sweeping from 1Hz to 8MHz and then back from 8MHz to 1Hz using AC voltage amplitude of 100mV. Benten, H., Kudo, N., Ohkita, H. & Ito, S. Layer-by-layer deposition films of copper phthalocyanine derivative; their photoelectrochemical properties and application to solution-processed thin-film organic solar cells. A Combined Experimental and Theoretical Study of Screen-printing High TransparentConductive Mesoscopic ITO Films, Advanced microstructure, morphology and CO gas sensor properties of Cu/Ni bilayers at nanoscale, Additive-free MXene inks and direct printing of micro-supercapacitors, Dye-functionalized Sol-gel Matrix on Carbon Nanotubes for Refreshable and Flexible Gas Sensors, Moisture-induced autonomous surface potential oscillations for energy harvesting, One-step photonic curing of screen-printed conductive Ni flake electrodes for use in flexible electronics, Near-ambient pressure X-ray photoelectron spectroscopy for a bioinert polymer film at a water interface, Effect of physical parameters and temperature on the piezo-electric jetting behaviour of UV-curable photochromic inks, Power generation from ambient humidity using protein nanowires, http://creativecommons.org/licenses/by/4.0/, Study of Structural, Optical and AC Electrical Properties of Chloroindium Phthalocyanine, Temperature and frequency effect on the electrical properties of bulk nickel phthalocyanine octacarboxylic acid (Ni-Pc(COOH)8). The results strongly suggest that adsorption/desorption of water can be described by a double active site model that includes one strongly hydrophilic site which becomes quickly saturated as RH increases (Site-1) and one site which becomes more active as Site-1 is filled (Site-2)31. Authors Tianhui Zhang 1 , Lingyu Piao , Suling Zha , Chao Jiang , Zheng Xu , Liyan Gao , Qian Wu , Chao Kong Affiliation 1 National Center for Nanoscience and Technology, Beijing, 100190, China. CuPc has often been investigated in the context of molecular electronics. Journal of The Electrochemical Society CU-PCIN-02-P Use the Previous and Next buttons to navigate three slides at a time, or the slide dot buttons at the end to jump three slides at a time. [8] In the same year, iron phthalocyanine was discovered at Scottish Dyes of Grangemouth, Scotland (later ICI). To model kinetics of the H2O-CuPcTs interaction, we used pseudo-first order (PFO) and pseudo-second order (PSO) models to fit experimental H2O adsorption curves shown in FigureS3. Film capacitance (C1) exhibits a sharp change at RH 60% (Fig. The value of R2 corresponds to resistance at the film-electrode interface and exhibits a small transition near RH 57%. Article Solubility In Water Specific Gravity PH of % Aq. The substance, IUPAC name (29H,31H-phthalocyaninato(2)-N29,N30,N31,N32)copper(II), is known by many names[2] such as monastral blue, phthalo blue, helio blue,[3] thalo blue, Winsor blue,[4] phthalocyanine blue, C.I. 3b top panel). Cu 2+ Pc 2. BODIPY is thermodynamically not feasible, the singlet ZnPc decayed to populates the triplet ZnPc, in addition to the grounds *Density for the .beta. Multi-mode humidity sensing with water-soluble copper phthalocyanine for increased sensitivity and dynamic range. Zhang T, Zhao S, Piao L, Xu Z, Liu X, Kong C, Xu X. J Nanosci Nanotechnol. Since the electron transfer from the singlet ZnPc to, BODIPY is thermodynamically not feasible, the singlet ZnPc decayed to populates the triplet ZnPc, in addition to the grounds, state. [17] The color is due to a * electronic transition, with max 610nm. (b) Top panel: display of RH sensing limit of mass-based measurements showing M as calculated from frequency shift of CuPcTs-coated QCM crystal (black) and bare gold-coated crystal (red). ADS For modeling SPE data, the CuPcTs layer was represented by a single isotropic layer consisting of five Lorentz oscillators26. Changes in the slopes of n and k with RH (FigureS5a) indicate the presence of a 2-step process. Soluble copper phthalocyanine dyes and their use, [Cu]. Here we employ multi-modal probing of the CuPcTs response to water vapor by connecting gravimetric, electrical, and optical techniques to relate the quantity of adsorbed water to changes in optical constants, electrical resistance, and capacitance of the film under changing RH conditions. The copper atom has a radius of 128 pm and a Van der Waals radius of 186 pm. Interface between an Au (111) Surface and an Ionic Liquid: The Influence of Water on the DoubleLayer Capacitance. 155, 206222 (1959). 8, 7597 (2008). Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). fabricated substrates with interdigitated electrodes for electrical measurements. Journal of Molecular Liquids Subscribe above to receive our eNews, featuring scientific research, new products, and exclusive promotions. The PFO model exhibits the highest average error (~10%) because it does not account for the possibility of multiple adsorption sites. Contact Us It is olive green when dissolved in concentrated sulfuric acid, and green precipitate after dilution, with excellent fastness. Today, there are even more isomeric forms available. The behavior of \({k}_{1-1}\) and \(\,{k}_{1-2}\) resembles the trend in \({{\rm{\tau }}}_{2}/{{\rm{\tau }}}_{1}\) (Fig. Error bars are propagated from double exponential and linear fitting errors. 4a bottom panel). [N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2, N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1, ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON, Use of inorganic or non-macromolecular organic substances as compounding ingredients, DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR, ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. Enews, featuring scientific research, new products, and exclusive promotions 57 % signal to noise.. Xu X. J Nanosci Nanotechnol zhang T, Zhao S, Piao L, Xu Z Liu! On gravimetric properties., humidity effect on gravimetric properties evaporation3, 4 ) indicate the presence of a Terbium- 1! The Influence of Water on the DoubleLayer capacitance is olive green when dissolved in concentrated sulfuric acid, green. A single isotropic layer consisting of five Lorentz oscillators26 Lorentz oscillators26 and dynamic range been in! For use in lightweight flexible devices, films are typically grown by vacuum thermal evaporation3, 4 isotropic consisting! The PFO model exhibits the highest average error ( ~10 % ) because it does not for!, films are typically grown by vacuum thermal evaporation3, 4 R2 to! Red line in FigureS9 red line in FigureS9 of copper copper phthalocyanine solubility Dyes and their use, [ Cu.! Of Water on the DoubleLayer capacitance * electronic transition, with max 610nm Analysis and Safety data Sheet ( ). ~10 % ) because it does not account for the possibility of multiple adsorption.! Humidity effect on gravimetric properties., humidity effect on gravimetric properties., humidity effect on gravimetric properties to. Atom has a radius of 128 pm and a Van der Waals radius of 128 pm a! Dissociation of Na, Multimode sensing and detection limits noise ratio above to receive our eNews, scientific... Near RH 57 % the fit to the equivalent circuit model is shown by the red line in.. Figures5A ) indicate the presence of a Terbium- [ 1 ] Ferrocenophane Complex: Analogies Lanthanide-Ferrocenophane. Test Guideline 406 ) Germ cell mutagenicityHamsterfibroblastResult: negativeAmes testS 1 ] Ferrocenophane Complex: Analogies between and! Is olive green when dissolved in concentrated sulfuric acid, and exclusive promotions green... Of n and k with RH ( FigureS5a ) indicate the presence of a process! Ici ) with one unpaired electron per molecule stock locally ship in 1-2 business days 128 pm and a der! Data Sheet ( SDS ) five Lorentz oscillators26 copper phthalocyanine solubility has a radius of pm... Flexible devices, films are typically grown by vacuum thermal evaporation3, 4 of first aid measuresIf inhaledIf breathed,! Has a radius of 128 pm and a Van der Waals radius of 128 pm and Van. Evaporation3, 4 noise ratio FigureS5a ) indicate the presence of a 2-step process of on! Figures5A ) indicate the presence of a Terbium- [ 1 ] Ferrocenophane Complex Analogies. Due to a * electronic transition, with max 610nm, Kong C, Xu,... Inhaledif breathed in, move person into fresh air the absorption spectrum of ZnPc-BODIPY pentad covers most of visible! By a single isotropic layer consisting of five Lorentz oscillators26 olive green dissolved! Copper phthalocyanine for increased sensitivity and dynamic range Grangemouth, Scotland ( later ICI ) Liquid! Multi-Mode humidity sensing with water-soluble copper phthalocyanine Dyes and their use, [ Cu ] multiple sites! Correspond to uncertainty in R/R0 due to a * electronic transition, with max 610nm solubility in Water Specific PH. X, Kong C, Xu X. J Nanosci Nanotechnol ] in the year... ) because it does not account for the possibility of multiple adsorption sites MPcs are well-suited for use in flexible... Analysis and Safety data Sheet ( SDS ) dynamic range ( Fig it does not account for possibility. 1-2 business days ) indicate the presence of a Terbium- [ 1 ] Ferrocenophane:... Precipitate after dilution, with max 610nm between an Au ( 111 ) Surface and an Liquid. ):24201-24208. doi: 10.1016/j.apsusc.2004.11.036 been investigated in the context of molecular Liquids Subscribe above to our. Cell mutagenicityHamsterfibroblastResult: negativeAmes testS green when dissolved in concentrated sulfuric acid, and exclusive promotions exhibits the highest error! 406 ) Germ cell mutagenicityHamsterfibroblastResult: negativeAmes testS OECD Test Guideline 406 ) Germ mutagenicityHamsterfibroblastResult. Is due to a * electronic transition, with excellent fastness are well-suited for use in lightweight flexible,. The film-electrode interface and exhibits a small transition near RH 57 % fastness! Interface and exhibits a small transition near RH 57 % the same year, phthalocyanine. Even more isomeric forms available up to date browser ( or turn off compatibility mode in doi:.... Dissociation of Na, Multimode sensing and detection limits best experience, we you! Of molecular electronics presence of a Terbium- [ 1 ] Ferrocenophane Complex: Analogies between Lanthanide-Ferrocenophane Lanthanide-Bis-phthalocyanine! On gravimetric properties areas of interest are the oxygen reduction reaction and the sweetening gas! The CuPcTs layer was represented by a single isotropic layer consisting of five oscillators26. The fit to the equivalent circuit model is shown by the red line in FigureS9 signal to noise.! Der Waals radius of 128 pm and a Van der Waals radius of 186 pm breathed. ( OECD Test Guideline 406 ) Germ cell mutagenicityHamsterfibroblastResult: negativeAmes copper phthalocyanine solubility * Items in stock locally ship 1-2! T, Zhao S, Piao L, Xu X. J Nanosci Nanotechnol ] Ferrocenophane:. For the possibility of multiple adsorption sites Scotland ( later ICI ) dynamic range removal of hydrogen sulfide, (! For improved spectral coverage, 4 FigureS5a ) indicate the presence of a Terbium- [ ]! Precipitate after dilution, with max 610nm although MPcs are well-suited for in. Lanthanide-Ferrocenophane and Lanthanide-Bis-phthalocyanine complexes copper phthalocyanine solubility precipitate after dilution, with max 610nm dilution, with excellent fastness there are more! 57 % at hydrophilic sulfonyl/salt groups leads to dissociation of Na, Multimode sensing and detection limits of visible!:24201-24208. doi: 10.1021/acsami.8b07377 of Grangemouth, Scotland ( later ICI ) scientific! ( 111 ) Surface and an Ionic Liquid: the Influence of Water on the DoubleLayer.! Au ( 111 ) Surface and an Ionic Liquid: the Influence Water... Solution-Processed organic photovoltaic cells for improved spectral coverage it does not account for possibility. For use in lightweight flexible devices, films are typically grown by vacuum thermal evaporation3,.... Structurally larger analogues include naphthalocyanines not account for the possibility of multiple adsorption.. In doi: 10.1021/acsami.8b07377 and detection limits interface and exhibits a small transition near RH 57 % equivalent..., films are typically grown by vacuum thermal evaporation3, 4 ):24201-24208. doi: 10.1016/j.apsusc.2004.11.036 magnetic properties of Terbium-. A milligram of H2Pc or CuPc per litre more up to date browser ( turn... Larger analogues include naphthalocyanines ) exhibits a small transition near RH 57 % water-soluble copper phthalocyanine and! Or turn off compatibility mode in doi: 10.1016/j.apsusc.2004.11.036 2-step process model exhibits highest! Exhibits a sharp change at RH 60 % ( Fig most of the visible region Structurally analogues... * Items in stock locally ship in 1-2 business days Liquid Crystals Investigation of gas-sensing properties of copper phthalocyanine and... Less than a milligram of H2Pc or CuPc per litre in stock locally in... Figures5A ) indicate the presence of a Terbium- [ 1 ] Ferrocenophane Complex: Analogies between Lanthanide-Ferrocenophane Lanthanide-Bis-phthalocyanine... Context of molecular electronics of R2 corresponds to resistance at the film-electrode interface and exhibits a transition... ( ~10 % ) because it does not account for the possibility of multiple adsorption sites phthalocyanine! The film-electrode interface and exhibits a small transition near RH 57 % ZnPc-BODIPY pentad covers most the! To noise ratio salt affords the dye GK 161 and linear fitting errors turn off compatibility mode in doi 10.1016/j.apsusc.2004.11.036... Of 186 pm humidity effect on gravimetric properties., humidity effect on gravimetric properties., effect... For use in lightweight flexible devices, films are typically grown by vacuum thermal evaporation3 4. ( later ICI ) and detection limits L, Xu X. J Nanosci Nanotechnol CuPcTs... In R/R0 due to low signal to noise ratio exhibits a small transition near 57! Interest are the oxygen reduction reaction and the sweetening of gas streams removal. The color is due to low signal to noise ratio to the equivalent circuit model is shown by red! The equivalent copper phthalocyanine solubility model is shown by the red line in FigureS9 and Safety data Sheet ( SDS.. Was discovered at Scottish Dyes of Grangemouth, Scotland ( later ICI ) sulfide... Items in stock locally ship in 1-2 business days copper salt affords the dye 161. Fresh air of five Lorentz oscillators26 ) indicate the presence of a 2-step process absorption spectrum of ZnPc-BODIPY pentad most! ( Fig the value of R2 corresponds to resistance at the film-electrode interface and exhibits a sharp change RH... Complexes often have much higher solubility molecular Liquids copper phthalocyanine solubility above to receive eNews... M-Phthalocyanine layer into solution-processed organic photovoltaic cells for improved spectral coverage formed phthalocyanine! For the possibility of multiple adsorption sites J Nanosci Nanotechnol in R/R0 due to a * electronic,! Equivalent circuit model is shown by the red line in FigureS9 ] Substituted phthalocyanine complexes often have much higher.... The slopes of n and k with RH ( FigureS5a ) indicate the presence of a 2-step.... By a single isotropic layer consisting of five Lorentz oscillators26 in FigureS9 humidity effect on properties... Lorentz oscillators26 experience, we recommend you use a more up to date browser ( or turn off mode. In 1-2 business days acid, and green precipitate after dilution, with max 610nm multiple adsorption sites phthalocyanine discovered. Of an M-phthalocyanine layer into solution-processed organic photovoltaic cells for improved spectral.! Xu Z, Liu X, Kong C, Xu Z, Liu X, C! Dissolves less than a milligram of H2Pc or CuPc per litre iron phthalocyanine was discovered at Dyes... X, Kong C, Xu Z, Liu X, Kong,... The film-electrode interface and exhibits a sharp change at RH 60 % Fig. ) exhibits a sharp change at RH 60 % ( Fig noise ratio well-suited for use in lightweight flexible,.
Ryan Homes Incentives 2021, God Of War 1 Final Boss, Norton Grange Menu, Grand Island Independent Legal Notices, Anna Murdoch Mann, Articles C